Pepeo pšenične slame kao katalizator proizvodnje biodizela Naučni rad
Bočna strana članka
Glavni sadržaj članka
Apstrakt
Pepeo pšenične slame (PPS) je korišćen kao katalizator u proizvodnji biodizela iz suncokretovog ulja. Karakterizacija katalizatora je izvršena primenom metoda temperaturski programiranom razgradnjom (temperature-programmed decomposition, TPDe), rentgenskom difrakcijom (X-ray diffraction, XRD), Hg porozimetrijom, N2 fizisorpcijom i skenirajućom elektronskom mikrosopijom sa energo-disperzivnom spektrometrijom (scanning electron microscopy and energy dispersive X-ray spectroscopy, SEM-EDS). Reakcija metanolize istraživana je pri sledećim reakcionim uslovima: temperaturni opseg 55-65 °C; količina katalizatora 10-20 % (računato na masu ulja) i opseg molskog odnosa methanol : ulje 18 : 1 – 24 : 1. Optimizacija reakcionih uslova izvršena je metodologijom površine odziva u kombinaciji sa istorijskim eksperimentalnim planom. Maksimalni prinos metil estara masnih kiselina (MEMK) od 98,6 % postignut je pri sledećim optimalnim reakcionim uslovima: temperatura 60,3 oC, količina katalizatora 11,6 % (računato na masu ulja), molski odnos methanol : ulje 18,3 : 1 i vreme trajanja reakcije 124 min. Vrednosti koeficijenata determinacije (R2 = 0,811, R2pred = 0,789, R2adj = 0,761) i srednjeg relativnog odstupanja (±10,6 %, 66 podataka) ukazali su na prihvatljivost i pouzdanost razvijenog modela. Sadržaj MEMK nakon 4 h reakcije pri optimalnim uslovima smanjen je na 37, 12 i 3 % nakon prve, druge i treće upotrebe katalizatora, redom.
Detalji članka
Broj časopisa
Rubrika
Ovaj rad je pod Creative Commons Aуторство-Nekomercijalno-Bez prerade 4.0 Internacionalna licenca.
Kada je rukopis prihvaćen za objavlјivanje, autori prenose autorska prava na izdavača. U slučaju da rukopis ne bude prihvaćen za štampu u časopisu, autori zadržavaju sva prava.
Na izdavača se prenose sledeća prava na rukopis, uklјučujući i dodatne materijale, i sve delove, izvode ili elemente rukopisa:
- pravo da reprodukuje i distribuira rukopis u štampanom obliku, uklјučujući i štampanje na zahtev;
- pravo na štampanje probnih primeraka, reprint i specijalnih izdanja rukopisa;
- pravo da rukopis prevede na druge jezike;
- pravo da rukopis reprodukuje koristeći fotomehanička ili slična sredstva, uklјučujući, ali ne ograničavajući se na fotokopiranje, i pravo da distribuira ove kopije;
- pravo da rukopis reprodukuje i distribuira elektronski ili optički koristeći sve nosioce podataka ili medija za pohranjivanje, a naročito u mašinski čitlјivoj/digitalizovanoj formi na nosačima podataka kao što su hard disk, CD-ROM, DVD, Blu-ray Disc (BD), mini disk, trake sa podacima, i pravo da reprodukuje i distribuira rukopis sa tih prenosnika podataka;
- pravo da sačuva rukopis u bazama podataka, uklјučujući i onlajn baze podataka, kao i pravo prenosa rukopisa u svim tehničkim sistemima i režimima;
- pravo da rukopis učini dostupnim javnosti ili zatvorenim grupama korisnika na osnovu pojedinačnih zahteva za upotrebu na monitoru ili drugim čitačima (uklјučujući i čitače elektonskih knjiga), i u štampanoj formi za korisnike, bilo putem interneta, onlajn servisa, ili putem internih ili eksternih mreža.
Kako citirati
Reference
Global Bioenergy Statistics 2019, World Bioenergy Association, 2019. https://worldbioenergy.org/uploads/191129%20WBA%20GBS%202019_HQ.pdf, Assessed 25.2.2021
Shan R, Lua L, Shi Y, Yuan H, Shi J. Catalysts from renewable resources for biodiesel production. Energy Convers Manage 2018; 178: 277-289. https://doi.org/10.1016/j.enconman.2018.10.032
Baskar G., I. Aberna Ebenezer Selvakumari, R. Aiswarya, Biodiesel production from castor oil using heterogeneous Ni doped ZnO nanocatalyst, Bioresour Technol. 2018; 250: 793-798. https://doi.org/10.1016/j.biortech.2017.12.010
Veličković AV, Avramović JM, Stamenković OS, Veljković VB. Kinetics of the sunflower oil ethanolysis using CaO as catalyst. Chem Ind Chem Eng Q. 2016; 22: 409-418. https://doi.org/10.2298/CICEQ160106003V
Nakomčić-Smaragdakis B, Čepić Z, Dragutinović N. Wheat straw combustion process and its impact on air pollution. Cont Agric Eng. 2014; 40: 50-62. UDK: 662.767.2:536.46
Etim AO, Betiku E, Ajala SO, Olaniyi PJ, Ojumu TV. Potential of ripe plantain fruit peels as an ecofriendly catalyst for biodiesel synthesis: Optimization by artificial neural network integrated with genetic algorithm. Sustainability. 2018; 10: 1-15. https://doi.org/10.3390/su10030707
Betiku E, Ajala SO. Modeling and optimization of Thevetia peruviana (yellow oleander) oil biodiesel synthesis via Musa paradisiacal (plantain) peels as heterogeneous base catalyst: A case of artificial neural network vs. response surface methodology. Ind Crops Prod. 2014; 53: 314-322. https://doi.org/10.1016/j.indcrop.2013.12.046
Odude VO, Adesina AJ, Oyetunde OO., O.O. Adeyemi, N.B. Ishola, A.O. Etim, E. Betiku, Application of agricultural waste-based catalysts to trans esterification of esterified palm kernel oil into biodiesel: A case of banana fruit peel versus cocoa pod husk. Waste Biomass Valor. 2017; 10: 877-888. https://doi.org/10.1007/s12649-017-0152-2
Betiku E, Akintunde AM, Ojumu TV. Banana peels as a biobase catalyst for fatty acid methyl esters production using napoleons plume (Bauhinia monandra) seed oil: A process parameters optimization study. Energy 2016; 103: 797-806. https://doi.org/10.1016/j.energy.2016.02.138
Gohain M, Devi A, Deka D. Musa balbisiana Colla peel as highly effective renewable heterogeneous base catalyst for biodiesel production. Ind Crops Prod. 2017; 109: 8-18. https://doi.org/10.1016/j.indcrop.2017.08.006
Balaji M, Niju S. A novel biobased heterogeneous catalyst derived from Musa acuminate peduncle for biodiesel production – Process optimization using central composite design. Energy Convers Manage. 2019; 189: 118-131. https://doi.org/10.1016/j.enconman.2019.03.085
Balaji M, Niju S. Banana peduncle - A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil. Renewable Energy 2020; 146: 2255-2269. https://doi.org/10.1016/j.renene.2019.08.062
Deka DC, Basumatary S. High quality biodiesel from yellow oleander (Thevetia peruviana) seed oil. Biomass Bioenergy 2011; 35: 1797-1803. https://doi.org/10.1016/j.biombioe.2011.01.007
Sarma AK, Kumar P, Aslam M, Chouhan APS. Preparation and characterization of Musa balbisiana Colla underground stem nano-material for biodiesel production under elevated conditions. Catal Lett. 2014; 144: 1344-1353. https://doi.org/10.1007/s10562-014-1206-8
Aslam M, Saxena P, Sarma AK. Green technology for biodiesel production from Mesua ferrea L. seed oil. Energy Environ. Res. 2014; 4 (2): 11-21. https://doi.org/10.5539/eer.v4n2p11
Betiku E, Etim AO, Pereao O, Ojumu TV. Two-step conversion of neem (Azadirachta indica) seed oil into fatty methyl esters using a heterogeneous biomass-based catalyst: An example of cocoa pod husk. Energy Fuels 2017; 31: 6182-6193. https://doi.org/10.1021/acs.energyfuels.7b00604
Vadery V, Narayanan BN, Ramakrishnan RM, Cherikkallinmel SK, Sugunan S, Narayanan DP, Sasidharan S. Room temperature production of jatropha biodiesel over coconut husk ash. Energy 2014; 70: 588-594. https://doi.org/10.1016/j.energy.2014.04.045
Hindryawati N, Maniam GP, Karim MR, Chong KF. Transesterification of used cooking oil over alkali metal (Li, Na, K) supported rice husk silica as potential solid base catalyst. Eng. Sci .Technol. Int. J. 2014; 17: 95-103. https://doi.org/10.1016/j.jestch.2014.04.002
Miladinović MR, Zdujić MV, Veljović ĐN, Krstić JB, Banković-Ilić IB, Veljković VB, Stamenković OS. Valorization of walnut shell ash as a catalyst for biodiesel production. Renewable Energy 2020; 147: 1033-1043. https://doi.org/10.1016/j.renene.2019.09.056
Kostić MD, Bazargan A, Stamenković OS, Veljković VB, McKay G. Optimization and kinetics of sunflower oil methanolysis catalyzed by calcium oxide-based catalyst derived from palm kernel shell biochar. Fuel 2016; 163: 304-313. https://doi.org/10.1016/j.fuel.2015.09.042
Laskar IB, Gupta R, Chatterjee S, Vanlalveni C, Rokhum L. Taming waste: Waste Mangifera indica peel as a sustainable catalyst for biodiesel production at room temperature. Renewable Energy 2020; 161: 207-220. https://doi.org/10.1016/j.renene.2020.07.061
Mendonça IM, Paes OARL, Maia PJS, Souza MP, Almeida RA, Silva CC, Duvoisin S Jr., de Freitas FA. New heterogeneous catalyst for biodiesel production from waste tucuma peels (Astrocaryum aculeatum Meyer): Parameters optimization study. Renewable Energy 2019; 130: 103-110. https://doi.org/10.1016/j.renene.2018.06.059
Uprety B.K, Chaiwong W, Ewelike C, Rakshit SK. Biodiesel production using heterogeneous catalysts including wood ash and the importance of enhancing byproduct glycerol purity. Energy Convers. Manage. 2016; 115: 191-199. https://doi.org/10.1016/j.enconman.2016.02.032
Aleman-Ramirez JL, Moreira J, Torres-Arellano S, Longoria A, Okoye PU, Sebastian PJ. Preparation of a heterogeneous catalyst from moringa leaves as a sustainable precursor for biodiesel production. Fuel 2021; 284: 118983. https://doi.org/10.1016/j.fuel.2020.118983
Barros S de S, Pessoa Junior WAG, Sá ISC, Takeno ML, Nobre FX, Pinheiro W, Manzato L, Iglauer S, de Freitas FA. Pineapple (Ananás comosus) leaves ash as a solid base catalyst for biodiesel synthesis. Bioresour Technol. 2020; 312: 123569. https://doi.org/10.1016/j.biortech.2020.123569
Nath B, Das B, Kalita P, Basumatary S. Waste to value addition: Utilization of waste Brassica nigra plant derived novel green heterogeneous base catalyst for effective synthesis of biodiesel. J Cleaner Prod. 2019; 239: 118112. https://doi.org/10.1016/j.jclepro.2019.118112
Kostić MD, Tasić MB, Đalović IG, Biberdžić MO, Mitrović PM, Stamenković OS, Veljković VB. Optimization of biodiesel production from corn oil by methanolysis catalyzed by corn cob ash. Recycl. Sustainable Dev. 2018; 11: 53-62. https://doi.org/10.5937/ror1801053K
Vinu V, Binitha NN. Lithium silicate based catalysts prepared using arecanut husk ash for biodiesel production from used cooking oil. Mater Today: Proc. 2020; 25: 241-245. https://doi.org/10.1016/j.matpr.2020.01.210
Changmai B, Rano R, Vanlalveni C, Rokhum L. A novel Citrus sinensis peel ash coated magnetic nanoparticles as an easily recoverable solid catalyst for biodiesel production. Fuel 2021; 286: 119447. https://doi.org/10.1016/j.fuel.2020.119447
Gouran A, Aghel B, Nasirmanesh F. Biodiesel production from waste cooking oil using wheat bran ash as a sustainable biomass. Fuel 2021; 295: 120542. https://doi.org/10.1016/j.fuel.2021.120542
Jaćimović G, Malešević M, Bogdanović D, Marinković B, Crnobarac J, Latković D, Aćin V. Wheat yield depending on long-term harvest residue incorporation. Letopis naučnih radova 2009; 33: 85-92. UDK: 633.11:631.82.
Kim SH, Gregory JM. Straw to grain ratio equation for combine simulation. J Biosyst Eng. 2015; 40: 314-319. http://dx.doi.org/10.5307/JBE.2015.40.4.314
Wieser H, Milijić V. Dostupnost poljoprivredne biomase u Srbiji, Deutsche Gesellschaft für Internationale Zusammenarbeit (GIZ) GmbH. Availability of agro-biomass in Serbia. 2017. http://www.bioenergy-serbia.rs/images/documents/studies/20171028_Agrobiomass_Study.pdf, Assessed January 4, 2020.
Khushnood RA, Rizwan SA, Memon SA, Tulliani J-M, Ferro GA. Experimental investigation on use of wheat straw ash and bentonite in self-compacting cementitious system. Adv. Mater. Sci. Eng. 2014; 2014: 832508. http://dx.doi.org/10.1155/2014/832508
Ahmad MR, Sharif MB, Ali HA, Hussain M, Chen B. Experimental investigation of pozzolanic concrete containing wheat straw ash. Can. J. Civ. Eng. 2019; 46: 941-951. https://doi.org/10.1139/cjce-2017-0419.
Amin MN, Murtaza T, Shahzada K, Khan K, Adil M. Pozzolanic potential and mechanical performance of wheat straw ash incorporated sustainable concrete. Sustainability 2019; 11: 519. https://doi.org/10.3390/su11020519.
Jankovský O, Pavlíková M, Sedmidubský D, Bouša D, Lojka M, Pokorný J, Záleská M, Pavlí Z. Study on pozzolana activity of wheat straw ash as potential admixture for blended cements. Ceram.-Silik. 2017; 61: 327-339. http://dx.doi.org/10.13168/cs.2017.0032
Memon SA, Wahid I, Khan MK, Tanoli MA, Bimaganbetova M. Environmentally friendly utilization of wheat straw ash in cement-based composites. Sustainability 2018; 10: 1322. https://doi.org/10.3390/su10051322
Qudoos A, Kim HG, Atta-ur-Rehman, Jeon IK, Ryou J-S. Influence of the particle size of wheat straw ash on the microstructure of the interfacial transition zone. Powder Technol. 2019; 352: 453-461. https://doi.org/10.1016/j.powtec.2019.05.005
Sharma G, Singh K. Agro-waste ash and mineral oxides derived glass-ceramics and their interconnect study with Crofer 22 APU for SOFC application. Ceram. Int. 2019; 45: 20501-20508. https://doi.org/10.1016/j.ceramint.2019.07.029
Bartůněk V, Sedmidubský D, Bouša D, Jankovský O. Production of pure amorphous silica from wheat straw ash. Green Mater. 2018; 6: 1-5. https://doi.org/10.1680/jgrma.17.00035
Dodson J. Wheat straw ash and its use as a silica source. 2011; Ph. D. Thesis, Univ. York, UK, 2011.
Pokorný J, Pavlíková M, Jankovský O, Łagód G, Pavlík Z. Properties of wheat straw ash geopolymer for construction use. In: Proceedings of 19th International Multidisciplinary Scientific GeoConference SGEM 2019. Sofia, Bulgary, 2019, pp. 239-246. https://doi.org/10.5593/sgem2019/6.2/S26.031
Wang X, Yao K, Huang X, Chen X, Yu G, Liu H, Wang F, Fan M. Effect of CaO and biomass ash on catalytic hydrogasification behavior of coal char. Fuel 2019; 249: 103-111. https://doi.org/10.1016/j.fuel.2019.03.025
Ali MMM, Ahmed MJ. Adsorption behavior of doxycycline antibiotic on NaY zeolite from wheat (Triticum aestivum) straws ash. J. Taiwan Inst. Chem. Eng. 2017; 81: 218-224. https://doi.org/10.1016/j.jtice.2017.10.026.
Kumar A, Mandal A, Singh N. Rice and wheat straw ashes: Characterization and modeling of pretilachlor sorption kinetics and adsorption isotherm. J. Environ. Sci. Health B 2019; 54: 303-312. https://doi.org/10.1080/03601234.2018.1561059
Trivedi NS, Kharkar RA, Mandavgane SA. Use of wheat straw combustion residues for removal of chlorinated herbicide (2,4-dichlorophenoxyacetic acid). Waste Biomass Valor. 2019; 10: 1323-1331. https://doi.org/10.1007/s12649-017-0134-4
Đokić-Stojanović DR, Todorović ZB, Troter DZ, Stamenković OS, Veselinović LjM, Zdujić MV, Manojlović DD, Veljković VB. Triethanolamine as an efficient cosolvent for biodiesel production by CaO-catalyzed sunflower oil ethanolysis: An optimization study. Hem. Ind. 2019; 73: 351-362.https://doi.org/10.2298/HEMIND190822033D
Stanković M, Krstić J, Gabrovska M, Radonjić V, Nikolova D, Lončarević D, Jovanović D. Supported nickel-based catalysts for partial hydrogenation of edible oils. In: New Advances in Hydrogenation Processes - Fundamentals and Applications. IntechOpen; 2017: https://dx.doi.org/doi.org/10.5772/66967, https://www.intechopen.com/chapters/53666
Rouquerol F, Rouquerol J, Sing K. Adsorption by Powders and Porous Solids, Principles, Methodology and Applications. London, Academic Press; 1999.
Dubinin MM. Progress in Surface and Membrane Science. New York, Academic Press; 1975.
Barrett EP, Joyner LG, Halenda PP. The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J. Am. Chem. Soc. 1951; 73: 373-380.
Lecloux A, Pirard JP. The importance of standard isotherms in the analysis of adsorption isotherms for determining the porous texture of solids. J Colloid Interface. Sci. 1979; 70: 265-281.
Veličković AV, Stamenković OS, Todorović ZB, Veljković VB. Application of the full factorial design to optimization of base-catalyzed sunflower oil ethanolysis. Fuel 2013; 104: 433-442. https://doi.org/10.1016/j.fuel.2012.08.015
Vassilev SV, Vassileva CG, Song YC, Li WY, Feng J. Ash contents and ash forming elements of biomass and their significance for solid biofuel combustion. Fuel 2017; 208: 377-409. https://doi.org/10.1016/j.fuel.2017.07.036
Singh B, Camps-Arbestain M, Lehmann J. Biochar: A guide to analytical methods. Australia, Clayton, Vic.: CSIRO Publishing; 2017.
Clemente JS, Beauchemin S, Thibault Y, MacKinnon T, Smith D. Differentiating inorganics in biochars produced at commercial scale using principal component analysis. ACS Omega 3 2018, 6: 6931-6944. https://doi. org /10.1021/acsomega.8b00523
Platonov AY, Evdokimov AN, Kurzin AV, Maiyorova HD. Solubility of Potassium Carbonate and Potassium Hydrocarbonate in Methanol. J. Chem. Eng. Data. 2002; 47: 1175-1176. https://doi/10.1021/je020012v
Lôbo IP, Ferreira SLC, da Cruz RS. Biodiesel: quality parameters and analytical methods. Quim. Nova 2009; 32: 1596-1608. https://doi.org/10.1590/S0100-40422009000600044
Lundstedt T, Seifert E, Abramo L, Thelin B, Nyström Å, Pettersen J, Bergman R. Experimental design and optimization. Chemom. Intell. Lab. Syst. 1998; 42: 3-40. https://doi.org/10.1016/S0169-7439(98)00065-3
Anderson MJ. Statistics Made Easy_ Blog.The DOE FAQ Alert. 10 (6). http://www.statease.com/news/faqalert10-06.html (2020). Accessed January 8, 2020.
Anderson MJ, Whitcomb PJ. RSM simplified: Optimizing processes using response surface methods for design of experiments. 2nd ed., New York, Productivity Press; 2005.
Vaz MAB, Pacheco PS, Seidel E Jr, Ansuj AP. Classification of the coefficient of variation to variables in beef cattle experiments. Cienc. Rural. 2017; 47: 1-4. http://dx.doi.org/10.1590/0103-8478cr20160946
Saldaña-Roblesa A, Guerra-Sánchez R, Maldonado-Rubio MI, Peralta-Hernández JM. Optimization of the operating parameters using RSM for the Fenton oxidation process and adsorption on vegetal carbon of MO solutions. J. Ind. Eng. Chem. 2014; 20: 848-857. https://doi.org/10.1016/j.jiec.2013.06.015