Ispitivanje efikasnosti prirodnog materijala za uklanjanje katjonskih oksazin- i anjonskih azo- boja iz vodenih rastvora Naučni rad
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U ovom radu je ispitan procese adsorpcije boja brijant krezol plave (BCB) i metil narandžaste (MeO) na ljuske semena bundeve sa lokalnog područja (LPSH). LPSH adsorbent je analiziran primenom infracrvene spektroskopije sa Furijeovom transformacijom, skenirajuće electronske mikroskopije sa spektroskopijom rendgenskih zraka disperzivne energije, difrakcije rendgenskih zraka i Brunauer-Emmett-Teller analizom. Deskriptivnom analizom morfologije LPSH utvrđena je heterogena površina, dok je strukturnom analizom utvrđeno prisustvo funkcionalnih grupa tipičnih za lignocelulozne strukture. Potvrđena je mezoporozna površina adsorbenta, specifične površine ~1,53 m2 g-1. Studije izotermne adsorpcije sugerišu da je Langmuirov model najbolje opisao adsorpciju MeO, dok je Frojndlihov model pogodniji za opisivanje adsorpcije BCB. Prema termodinamičkim analizama, adsorpcija BCB je bila egzotermna i spontana, dok je adsorpcija MeO bila endotermna i nespontana. Rezultati procene efikasnosti LPSH adsorbenta su pokazali da su maksimalni kapaciteti adsorpcije ~81 mg g-1 za BCB boju i ~8,2 mg g-1 za MeO boju.
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