CELLULOSE ACETATE BUTYRATE GRAPHENE OXIDE NANOCOMPOSITE MEMBRANE: FABRICATION, CHARACTERIZATION AND PERFORMANCE
Article Sidebar
Main Article Content
Abstract
In this study, the effects of graphene oxide (GO) nanosheets on the physicochemical properties and performances of cellulose acetate butyrate (CAB) membranes were investigated. Nanocomposite membranes were fabricated using CAB and a small amount of GO in the range of 0 to 0.07 wt.%, using a conventional phase-inversion method. Membranes were characterized by different methods and their performances were tested using a dead-end filtration system. Compared with pristine CAB membrane, experimental results demonstrated an improvement in features such as hydrophilicity, permeability, salt rejection, antifouling, and stability. The results proved an increase in the porosity and pore sizes of membranes with GO addition. Furthermore, the membrane containing 0.07 wt.% of GO exhibited a low contact angle of 37° and a dramatic improvement in water flux of about 450% (from 2 to 11 L/(m2 h)). Moreover, it demonstrated a salt rejection of 39% for NaCl and 87% for Na2SO4, corresponding to improvements of about 144 and 93%, respectively. Furthermore, the results revealed a higher antifouling property with an 86% improvement in flux recovery and higher stability in terms of performance and thermal properties compared to CAB.
Article Details
Issue
Section
Authors who publish with this journal agree to the following terms:
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
Authors grant to the Publisher the following rights to the manuscript, including any supplemental material, and any parts, extracts or elements thereof:
- the right to reproduce and distribute the Manuscript in printed form, including print-on-demand;
- the right to produce prepublications, reprints, and special editions of the Manuscript;
- the right to translate the Manuscript into other languages;
- the right to reproduce the Manuscript using photomechanical or similar means including, but not limited to photocopy, and the right to distribute these reproductions;
- the right to reproduce and distribute the Manuscript electronically or optically on any and all data carriers or storage media – especially in machine readable/digitalized form on data carriers such as hard drive, CD-Rom, DVD, Blu-ray Disc (BD), Mini-Disk, data tape – and the right to reproduce and distribute the Article via these data carriers;
- the right to store the Manuscript in databases, including online databases, and the right of transmission of the Manuscript in all technical systems and modes;
- the right to make the Manuscript available to the public or to closed user groups on individual demand, for use on monitors or other readers (including e-books), and in printable form for the user, either via the internet, other online services, or via internal or external networks.
How to Cite
References
C. Güell, R.H. Davis, J. Membr. Sci. 119 (1996) 269-284
A. Akthakul, R.F. Salinaro, A.M. Mayes, Macromolecules 37 (2004) 7663-7668
P. Wang, K.L. Tan, E.T. Kang, K.G. Neoh, J. Adhes. Sci. Technol. 16 (2002) 111-127
F. Liu, C.H. Du, B.K. Zhu, Y.Y. Xu, Polymer 48 (2007) 2910-2918
A.A. El-Zahhar, M.M. Alghamdi, B.M. Asiri, Desalin. Water Treat. 155 (2019) 381-389
H. Rabiee, V. Vatanpour, M.H.D.A. Farahani, H. Zarrabi, Sep. Purif. Technol. 156 (2015) 299-310
V. Vatanpour, M. Esmaeili, M.H.D.A. Farahani, J. Membr. Sci. 466 (2014) 70-81
V. Vatanpour, S.S. Madaeni, A.R. Khataee, E. Salehi, S. Zinadini, H.A. Monfared, Desalination 292 (2012) 19-29
M.M. Alghamdi, A.A. El-Zahhar, B.M. Asiri, Desalin. Water Treat. 165 (2019) 54-62
M.S. Sri Abirami Saraswathi, A. Nagendran, D. Rana, J. Mater. Chem., A 7 (2019) 8723-8745
T. Shibutani, T. Kitaura, Y. Ohmukai, T. Maruyama, S. Nakatsuka, T. Watabe, H. Matsuyama, J. Membr. Sci. 376 (2011) 102-109
X.Y. Qiu, S.W. Hu, Materials 6 (2013) 738-781
A. Shanbhag, B. Barclay, J. Koziara, P. Shivanand, Cellulose 14 (2007) 65-71
S. Vetrivel, D. Rana, M.S. Sri Abirami Saraswathi, K. Divya, N.J. Kaleekkal, A. Nagendran, Polym. Adv. Technol. 30 (2019) 1943-1950
S. Vetrivel, M.S.A. Saraswathi, D. Rana, A. Nagendran, Int. J. Biol. Macromol. 107 (2018) 1607-1612
B.X. Han, D.L. Zhang, Z.Q. Shao, L.L. Kong, S.Y. Lv, Desalination 311 (2013) 80-89
R.K. Joshi, S. Alwarappan, M. Yoshimura, V. Sahajwalla, Y. Nishina, Appl. Mater. Today 1 (2015) 1-12
R. Van Noorden, Nature 442 (2006) 228-229
Y. Wei, Y. Zhang, X. Gao, Z. Ma, X. Wang, C. Gao, Carbon 139 (2018) 964-981
A. Nicolaï, B.G. Sumpter, V. Meunier, Phys. Chem. Chem. Phys. 16 (2014) 8646-8654
Q. Xu, H. Xu, J. Chen, Y. Lv, C. Dong, T.S. Sreeprasad, Inorg. Chem. Front. 2 (2015) 417-424
J. Zhang, Z. Xu, M. Shan, B. Zhou, Y. Li, B. Li, J. Niu, X. Qian, J. Membr. Sci. 448 (2013) 81-92
G.S. Lai, W.J. Lau, P.S. Goh, A.F. Ismail, N. Yusof, Y.H. Tan, Desalination 387 (2016) 14-24
J. Zhang, Z. Xu, W. Mai, C. Min, B. Zhou, M. Shan, Y. Li, C. Yang, Z. Wang, X. Qian, J. Mater. Chem., A 1 (2013) 3101-3111
S. Zinadini, A.A. Zinatizadeh, M. Rahimi, V. Vatanpour, H. Zangeneh, J. Membr. Sci. 453 (2014) 292-301
L.M. Camacho, T.A. Pinion, S.O. Olatunji, Sep. Purif. Technol. 240 (2020) 116645
S.M. Ghaseminezhad, M. Barikani, M. Salehirad, Composites, B 161 (2019) 320-327
Y. Jahani, Desalin. Water Treat. 164 (2019) 62-74
R.J. Lee, Z.A. Jawad, A.L. Ahmad, H.B. Chua, Process Saf. Environ. Prot. 117 (2018) 159-167
P. Kunthadong, R. Molloy, P. Worajittiphon, T. Leejark-pai, N. Kaabbuathong, W. Punyodom, J. Polym. Environ. 23 (2015) 107-113
A.D. Sabde, M.K. Trivedi, V. Ramachandhran, M.S. Hanra, B.M. Misra, Desalination 114 (1997) 223-232
R.J. Lee, Z.A. Jawad, A.L. Ahmad, J.Q. Ngo, H.B. Chua, Improvement of CO2/N-2 separation performance by polymer matrix cellulose acetate butyrate, in: A. Saptoro, W.S. Khur, L.S. Wei, W.P.Q. Ng, M. Anwar, C. Yeo, K.E. Huey (Eds.), 29th Symposium of Malaysian Chemical Engineers, 2017
P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Z. Xu, H. Zhu, ACS Nano 7 (2013) 428-437
S. Liu, T.H. Zeng, M. Hofmann, E. Burcombe, J. Wei, R. Jiang, J. Kong, Y. Chen, ACS Nano 5 (2011) 6971-6980
J.-F. Li, Z.-L. Xu, H. Yang, L.-Y. Yu, M. Liu, Appl. Surf. Sci. 255 (2009) 4725-4732
V. Vatanpour, S.S. Madaeni, R. Moradian, S. Zinadini, B. Astinchap, Sep. Purif. Technol. 90 (2012) 69-82
R. Han, S. Zhang, C. Liu, Y. Wang, X. Jian, J. Membr. Sci. 345 (2009) 5-12
S. Bose, T. Kuila, M.E. Uddin, N.H. Kim, A.K.T. Lau, J.H. Lee, Polymer 51 (2010) 5921-5928
X. Chang, Z. Wang, S. Quan, Y. Xu, Z. Jiang, L. Shao, Appl. Surf. Sci. 316 (2014) 537-548
P. Shanmugaraj, A. Swaminathan, R.K. Ravi, M. Dasaiah, P. Senthil Kumar, A. Sakunthala, J. Mater. Sci.-Mater. Electron. 30 (2019) 20079-20087
J. Alongi, G. Malucelli, Thermal Degradation of Cellulose and Cellulosic Substrates, in: Reactions and Mech¬anisms in Thermal Analysis of Advanced Materials, A. Tiwari, B. Raj (Eds.), Beverly, Hoboken, NJ, 2015, pp. 301-332
N. Ghaemi, S.S. Madaeni, A. Alizadeh, P. Daraei, A.A. Zinatizadeh, F. Rahimpour, Sep. Purif. Technol. 85 (2012) 147-156
Y. Shi, C. Li, D. He, L. Shen, N. Bao, J. Mater. Sci. 52 (2017) 13296-13306
X. Fu, T. Maruyama, T. Sotani, H. Matsuyama, J. Membr. Sci. 320 (2008) 483-491
P. Daraei, S.S. Madaeni, N. Ghaemi, E. Salehi, M.A. Khadivi, R. Moradian, B. Astinchap, J. Membr. Sci. 415-416 (2012) 250-259
Y. Han, Y. Jiang, C. Gao, ACS Appl. Mater. Interfaces 7 (2015) 8147-8155
J.-n. Shen, H.-m. Ruan, L.-g. Wu, C.-j. Gao, Chem. Eng. J. 168 (2011) 1272-1278
S. Ansari, A.R. Moghadassi, S.M. Hosseini, Desalination 357 (2015) 189-196
A. Gholami, A.R. Moghadassi, S.M. Hosseini, S. Shab-ani, F. Gholami, J. Ind. Eng. Chem. 20 (2014) 1517-1522
B.S. Lalia, V. Kochkodan, R. Hashaikeh, N. Hilal, Desal¬ination 326 (2013) 77-95
C.A. Smolders, A.J. Reuvers, R.M. Boom, I.M. Wienk, J. Membr. Sci. 73 (1992) 259-275
X. Chang-Fa, L. Zhao-Feng, J. Appl. Polym. Sci. 41 (1990) 439-444
P. Daraei, S.S. Madaeni, N. Ghaemi, H. Ahmadi Monfa-red, M.A. Khadivi, Sep. Purif. Technol. 104 (2013) 32-44
B.M. Ganesh, A.M. Isloor, A.F. Ismail, Desalination 313 (2013) 199-207
S.L. Ong, W.W. Zhou, L.F. Song, W.J. Ng, Environ. Eng. Sci. 19 (2002) 429-439
Y. He, G.-M. Li, H. Wang, Z.-W. Jiang, J.-F. Zhao, H.-X. Su, Q.-Y. Huang, J. Taiwan Inst. Chem. Eng. 40 (2009) 289-295
L. Jin, W. Shi, S. Yu, X. Yi, N. Sun, C. Ma, Y. Liu, Desalination 298 (2012) 34-41
L.M. Jin, S.L. Yu, W.X. Shi, X.S. Yi, N. Sun, Y.L. Ge, C. Ma, Polymer 53 (2012) 5295-5303
S.S. Madaeni, N. Ghaemi, J. Membr. Sci. 303 (2007) 221-233
S.S. Madaeni, S. Zinadini, V. Vatanpour, J. Membr. Sci. 380 (2011) 155-162
K. Nakamura, K. Matsumoto, J. Membr. Sci. 280 (2006) 363-374
V. Vatanpour, S.S. Madaeni, R. Moradian, S. Zinadini, B. Astinchap, J. Membr. Sci. 375 (2011) 284-294.