Primena impregnisanog biouglja proizvedenog iz sojinih ljuspica u procesu obezbojavanja boje
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U cilju moguće valorizacije, otpadne sojine ljuspice (engl. waste soybean hulls, OSLj) su ispitivane kao nosači jona Fe, u dve različite forme: sirovoj i karbonizovanoj (engl. biocarbon, BU). Impregnacija jonima Fe(III) je implementirana radi sinteze heterogenih Fenton katalizatora (Fe-OSLj i Fe-BU) za obezbojavanje vodenog rastvora Reactive Blue 4 (RB4) boje. Karakterizacija materijala je pokazala porast specifične površine zbog dekompozicije konstituenata OSLj tokom karbonizacije (prilikom dobijanja BU) i termalne aktivacije (prilikom dobijanja Fe-OSLj i Fe-BU), gde su dobijeni katalizatori visoke mezoporoznosti sa hematitom kao aktivnom fazom za odvijanje Fentonove reakcije. Među pripremljenim materijalima, Fe-OSLj je pokazao značajnu sposobnost produkcije •OH radikala u kiseloj sredini. Dalje, optimizacija heterogenog Fenton procesa je izvedena primenom metodologije odzivnih površina (engl. Respose Surface Methodology, RSM), gde su redukovanim modelom izdvojeni sledeći uslovi reakcije: 3 mM H2O2, 100 mg Fe-OSLj, vreme reakcije od 180 min, pri konstantnim vrednostima pH = 3, koncentracije boje od 50 mg RB4 dm-3 i na sobnoj temperaturi. Postignuto je 88,7% i 66,8% obezbojavanja i mineralizacije RB4 boje, redom; Fe-OSLj je pokazao veliku stabilnost, a reakcioni intermedijeri formirani tokom oksidacionog procesa su imali mali inhibitorni efekat na Vibrio fischeri bakterije.
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