Primena EDS analize u ispitivanju metal-keramičkih međuspojeva višestruko livenih nikl-hrom dentalnih legura

Main Article Content

Vladimir B. Stefanović
Zoran R. Lazić
Nemanja J. Mirković
Ervin E. Taso
Nenad M. Simeunović
Jovica z. Nešić

Abstract

Eksperimentalna studija je sprovedena sa ciljem da se kvantifikuju promene metal-keramičkog međuspoja dentalnih nikl-hrom legura koje su podvrgnute ponovnom livenju - recikliranju. EDS analizom metal-keramičkih međuspojeva potrebno je utvrditi da li recikliranje dentalnih legura ima negativan uticaj na sastav metal-keramičkih međuspojeva zubnih nadoknada. Ispitivanje je obavljeno na nikl-hrom leguri tipa "Wiron 99", proizvođača "BEGO" (Nemačka). Rezultati EDS analize su pokazali smanjenje zastupljenosti metalnih komponenti legure u metal-keramičkom međuspoju, koje je u direktnoj zavisnosti sa povećanjem broja livenja legure. Utvrđen je pad koncentracije nikla, hroma, cerijuma, niobijuma i molibdena u međuspoju nakon 12 livenja legure. Od svih elemenata legure najviše se smanjio udeo cerijumau međuspoju , sa 28 wt% na 16,26 wt%. Koncentracija nikla je pala sa 3,31 wt% na 1,82 wt%, hroma sa 2,95 wt% na 2,03 wt%, molibdena sa 8,71 wt% na 4,68 wt%, a niobijuma sa 9,82 wt% na 3,97 wt%. Ponovna upotreba bazičnih dentalnih legura se ne može preporučiti zbog smanjenja koncentracije elemenata legure u metal-keramičkom međuspoju.

Downloads

Download data is not yet available.

Article Details

How to Cite
Stefanović, V. B., Lazić, Z. R., Mirković, N. J., Taso, E. E., Simeunović, N. M., & Nešić, J. z. (2018). Primena EDS analize u ispitivanju metal-keramičkih međuspojeva višestruko livenih nikl-hrom dentalnih legura. HEMIJSKA INDUSTRIJA (Chemical Industry), 72(3), 149–156. https://doi.org/10.2298/HEMIND180103009S
Section
Engineering of Materials - Metal materials
Author Biographies

Vladimir B. Stefanović, Vojnomedicinska akademija, Beograd

Specijalista bolesti zuba - VMA.

Doktorske studije - Kragujevac.

 

Zoran R. Lazić, Vojnomedicinska akademija, Beograd

Specijalista oralne hirurgije i implantologije.

Doktor stomatoloških nauka. Profesor na katedri za oralnu hirurgiju VMA.

Načelnik klinike za stomatologiju VMA.

Predavač na stomatološkom fakultetu u Pančevu.

Nemanja J. Mirković, Vojnomedicinski centar Slavija, Beograd

Magistar stomatoloskih nauka - VMA.

Specijalista stomatoloske protetike.

Ervin E. Taso, Vojnomedicinska akademija, Beograd

Specijalista stomatološke protetike VMA.

Doktorske studije.

Nenad M. Simeunović, Vojnomedicinski centar Slavija, Beograd

Načelnik odeljenja stomatologije - VMC Slavija.

Jovica z. Nešić, Vojnotehnički institut, Beograd

Dipl. inženjer.

Saradnik na katedri Vojne akademije za hemijsko inženjerstvo.

References

Divya G, Ramesh PN, Raghunath P. Evaluation and comparasion of effect of different surface threatments and varying alloy percentage on the elemental composition of Ni Cr base metal alloy. BJAST. 2016; 16(4): 1-12.

Craig RG, Powers JM, Wataha JC, editors. Dental Materials – Properties and Manipulations. St. Louis: Mosby; 2000.

McLean JW, editor. Dental Ceramics – Proceedings of the First International Symposium on Ceramics. Chicago: Quintessence Publishing Company; 1983.

Mackert JR, Parry EE, Fairhurst CW. Oxide adherence to a Ni-Cr-Mo ternary alloy. Dent Mater. 1985; 1: 111-4.

Mackert JR, Parry EE, Fairhurst CW. Oxide morphology and adherence on dental alloys designed for porcelain bonding. Oxid Met. 1986; 25: 319-33.

Anusavice KJ, Ringle RD, Fairhurst CW. Bonding mechanism evidence in a ceramic-nonprecious alloy system. J Biomed Mater Res. 1977; 11: 701-9.

Hofstede TM, Ercoli C, Graser GN, Tallents RH, Moss ME, Zero DT. Influence of metal surface finishing on porcelain porosity and beam failure loads at the metal-ceramic interface. J Prosthet Dent. 2000; 84: 309-17.

Wagner WC, Asgar K, Bigelow WC, Flinn RA. Effect of interfacial variables on metal-porcelain bonding. J Biomed Mater Res. 1993; 27: 531-7.

McLean JW, Odont D. Evaluation of dental ceramics in twentieth century. J Prosthet Dent. 2001; 85: 61-6.

Özcan M, Niedermeirer W. Clinical study on the reasons and location of failures of metal-ceramicrestorations and survival of repairs. Int J Prosthodont. 200215: 299-302.

Goodacre CJ, Bernal G, Rungscharassaeng K, Kan JY. Clinical complications in fixed prosthodontics. J Prosthet Dent. 2003; 90: 31-41.

Özcan M. Fracture reasons in ceramic-fused-to-metal restorations. J Dent Rehab. 2003; 30: 265-9.

Wang H, Feng Q, Li N, Xu S. Evaluation of metal-ceramic bond characteristics of three dental Co-Cr alloys prepared with different fabrication techniques. J Prosthet Dent. 2016; 116(6): 916-923.

Ali Z, Eliyas S, Vere JW. choosing the right dental material and making sense of the options: evidence and clinical recommendations. Eur J Prosthodont Restor Dent. 2015; 23(3): 150-62.

Kul E, Aladag LI, Duymus ZY. Comparison of the metal-ceramic bond after recasting and after laser sintering. J Prosthet Dent. 2015; 114(1): 109-13.

Bulbule N, Motwani BK. Comparative study of fracture resistance of porcelain in metal ceramic restorations by using different metal coping designs- an in vitro study. J Clin Diagn Res. 2014; 8(11): 123-7

Galiatsatos AA, Galiatsatos PA. Galiatsatos AA, Galiatsatos PA. Clinical evaluation of fractured metal-ceramic fixed dental prostheses repaired with indirect technique. Quintessence Int. 2015; 46(3): 229-36.

Hong JM, Razoog ME, Lang BR. The effect of recasting on the oxidation layer of a palladium-silver porcelain alloy. J Prosthet Dent. 1988; 59: 420-5.

Nelson DR, Palik JF, Morris HF, Comella MC. Recasting a nickel-chromium alloy. J Prosthet Dent. 1986; 55: 122-7.

Preswood RG. Multiple recast of a nickel-chromium-beryllium alloy. J Prosthet Dent. 1983; 50: 198-9.

Sharma A, Rodrigues SJ, Shetty TB, Shenoy VK, Mundathaje M, Saldanha S. Evaluation of effect of recasting of nickel-chromium alloy on its castability using different investment materials: An in vitro study. Indian J Dent Res. 2016; 27(2): 190-4.

Agrawal A, Hashmi SW, Rao Y, Garg A. Evaluation of surface roughness and tensile strength of base metal alloys used for crown and bridge on recasting (recycling). J Clin Diagn Res. 2015; 9(7): 01-4.

Vaillant-Corroy AS, Corne P, De March P, Fleutot S, Cleymand F. Influence of recasting on the quality of dental alloys: A systematic review. J Prosthet Dent. 2015; 114(2): 205-11.

Madani AS, Rokni SR, Mohammadi A, Bahrami M. The effect of recasting on bond strength between porcelain and base-metal alloys. J Prosthodont. 2011; 20(3): 190-4.

Liu R, Johnston WM, Holloway JA, Brantley WA, Dasgupta T. The effect of metal recasting on porcelain-metal bonding: a force-to-failure study. J Prosthet Dent. 2010; 104(3): 165-72.

Atluri KR, Vallabhaneni TT, Tadi DP, Vadapalli SB, Tripuraneni SC, Averneni P. comparative evaluation of metal-ceramic bond strengths of nickel chromium and cobalt chromium alloys on repeated castings: An In vitro Study. J Int Oral Health. 2014; 6(5): 99-103.

Mackert JR, Parry EE, Hashinger DT, Fairhurst CW. Measurment of oxide adherence to PMF alloys. J Dent Res. 1984; 63: 1335-40.

Baran G. Oxidation kinetics of some Ni-Cr alloys. J Dent Res. 1983; 62: 51-5.

Baran G. Auger chemical analysis of oxides on Ni-Cr alloys. J Dent Res. 1984; 63: 76-80.

Bumgardner JD, Lucas LC. Surface analysis of nickel-chromium dental alloys. Dent Mater. 1993; 9: 252-9.

Baran GR. Oxide compounds on Ni-Cr alloys. J Dent Res 1984; 63: 1332-34.

Marks RA, Chapman DR, Danielson DT, Glaeser AM. Joining of alumina via copper/niobium/copper interlayers. Acta Mater. 2000; 48: 4225-38.

Anusavice KJ, Ringle RD, Fairhurst CW. Adherence controlling elements in ceramic-metal systems. I. Nonprecious alloys. J Dent Res. 1977; 56: 1053-61.

Trifunović D. Mehanizam vezivanja porcelanskih masa sa metalnim legurama i ponašanje ovakvih sistema u ljudskom organizmu [disertacija]. Beograd: Stomatološki fakultet; 1974.

Anusavice KJ, Horner JA, Fairhurst CW. Adherence controlling elements in ceramic-metal systems. I. Precious alloys. J Dent Res. 1977; 56: 1045-52.

Schäfer A, Päßler K. Bond Strenght of baked porcelain on nonprecious alloy after repeated pouring. Quint Zahntech. 1988; 14: 1403-9.

Ibrahim RM. Scanning and electron microprobe analysis of metal-porcelain interface. Egypt Dent J. 1995; 41: 1469-78.

Hegedűs C, Daróczi L, Kökényesi V, Beke DL. Comparative microstructural study of the diffusion zone between NiCr alloy and different dental ceramics. J Dent Res. 2002; 81: 334-7.

Yilmaz H, Dincer C. Comparasion of the bond compatibility of titanium and an Ni Cr alloy to dental porcelain. J Dent. 1999; 27: 215-22.

Lubovich RP, Goodkind RJ. Bond strenght studies of precious, semiprecious, and nonprecious ceramic-metal alloys with two porcelains. J prosthet Dent 1977; 37: 288-99.

Trifunović DM, Gligić M , Todorović AB. Ispitivanje Co-Cr-Mo legura u metal-keramici. Stomatološki glasnik Srbije. 1990; 4: 369-74.

Bullard JT, Dill RD, Marker VA, Payne EV. Effects of sputtered metal oxide films on the ceramic-to-metal bond. J Prosthet Dent. 1985; 54: 776-8.

Killbourn BT, editor. Cerium, a Guide to its Role in Chemical Technology. Mountain Pass: Molycorp Inc.; 1992.

Meenakshi T, Bharathi M, Komala J. Evaluation of the effect of recasting nickel-chromium base metal alloy on the metal-ceramic bond strength: an in vitro study. J Contemp Dent Pract. 2017; 18(9): 837-841