Uticaj temperature na fizičkohemijska svojstva eutektičkih rastvarača sa lecitinom i njihova upotreba u transesterifikaciji katalizovanoj CaO Naučni rad
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Zbog različitih strukturnih varijacija i mogućnosti prilagođavanja njihovih fizičkohemijskih svojstava, eutektički rastvarači se nazivaju ,,dizajnerski rastvarači”. Za industrijsku primenu eutektičkih rastvarača, važno je poznavati njihova fizička i termodinamička svojstva poput gustine, viskoziteta i indeksa prelamanja. Ova svojstva su merena u funkciji temperature za tri eutektička rastvarača lecitina sa glicerolom, trietanolaminom i oleinskom kiselinom. Za opisivanje viskoziteta primenjene su Arenijusova i jednačina Vogela, Tamana i Fulčera (Vogel-Tamman-Fulcher). Gustina, viskozitet i indeks prelamanja testiranih eutektičkih rastvarača opadali su sa porastom temperature. Eutektički rastvarač lecitin:glicerol (LEC:G) je imao najmanju gustinu na svim testiranim temperaturama. Na kraju, eutektički rastvarač LEC:G je izabran kao kosolvent u etanolizi hladno ceđenog ulja semena crne slačice (Brassica nigra L.) katalizovanoj žarenim ili nežarenim CaO. Reakcija je izvedena u šaržnom reaktoru uz stalno mešanje i pri sledećim reakcionim uslovima: temperatura 70 °C, molski odnos etanol-ulje 12:1, koncentracija eutektičkog rastvarača 20 mas. % (u odnosu na masu ulja) i koncentracija CaO 10 mas. % (u odnosu na masu ulja). Prisustvo eutektičkog rastvarača ubrzalo je reakciju i separaciju faza finalne reakcione smeše..
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Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-68/2022-14/200133 -
Serbian Academy of Sciences and Arts
Grant numbers 0-14-18
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