Mineraloške i kristalografske osobine zeolitskog tufa HEU-tipa lokaliteta Novaković, Bosna i Hercegovina

Main Article Content

Ana S. Radosavljević-Mihajlović
Aleksandra Daković
Vladan D. Kašić
Vojislav V. Mitić
Jovica N. Stojanović
Miroslav D. Sokić
Branislav R. Marković

Abstract

U radu su predstavljeni rezultati mineraloške i strukturne analize zeolitskog tufa lokaliteta Novaković, u Bosni i Hercegovini. Tuf je beličaste boje, osnovni mineralni sastav je mineral iz serije hejlandita – Ca-klinoptilolit. Prateća komponenta je amorfna faza, vulkansko staklo i amorfni SiO2. Ispitivanjem termičke stabilnosti, utvrđeno je da je struktura zeolita stabilna do 600 oC. Određivana je i struktura Ca-klinoptilolita u zeolitskom tufu. Struktura je utačnjavana u prostornoj grupi C2/m, sa neuređenom raspodelom Al i Si u tetraedarskoj mreži. Za ispitivanje su korišćene metode rendgenske difrakcije praha na polikristalnom uzorku (XRD, X-Ray powder diffraction analysis), skenirajuće elektronske mikroskopije i energodisperzivne spektroskopije x-zracima (SEM/EDS, scanning electron microscopy and energy dispersive spectroscopy analysis) i diferencijalno termička i diferencijalno termogra­vimetrijska analiza (DTA/DTG, differential thermal and thermogravimetric analysis).

Downloads

Download data is not yet available.

Article Details

How to Cite
Radosavljević-Mihajlović, A. S., Daković, A., Kašić, V. D., Mitić, V. V., Stojanović, J. N., Sokić, M. D., & Marković, B. R. (2018). Mineraloške i kristalografske osobine zeolitskog tufa HEU-tipa lokaliteta Novaković, Bosna i Hercegovina. HEMIJSKA INDUSTRIJA (Chemical Industry), 72(6), 371–382. https://doi.org/10.2298/HEMIND180725026R
Section
Applied Chemistry

References

Radosavljević-Mihajlović A., Matović B. Prirodni zeoliti i mogućnost njihove primene u zaštiti životne sredine, Nauka, Tehnika, Bezbednost, NBP, Journal of criminalistic and law 2008, 13(2): 107-119.

Gottardi G., Galli E. Natural Zeolites. Springer-Verlag, Berlin, 1985.

Barrer R.M. Zeolites and Clay Minerals as Sorbent and Molecular Sieves, Academi Press, New York, 1978.

Betekhtine A.G., Manuel de Mineralogie Descriptive. Editions MIR, Moscow, 659-666, 1968.

Douglas S.C., Alberto A., Armbruster T., Artioli G., Colella C., Galli E., Grice J.D., Liebau F., Mandarino J.A., Minato H., Nickle E.H., Passaglia E., Peacor D.R., Quartieri S., Rinaldi R., Ross M.I., Sheppard R.A., Tillmanns E., Vezzalini G. Recommended nomenclature for zeolite minerals: Report of the subcommittee on zeolites of the international mineralogical association, commission on new minerals and mineral names, Can Mineral 1997, 35: 1571-1606.

Mumpton F. Occurrence, Properties and Utilization of Natural Zeolites. In D. Kallo and H. S. Sherry, Eds., Akademiai Kiado, Budapest, 1988.

Breck D.W. Zeolite Molecular Sieves. Krieger Publ.Comp., Malabar, Florida, pp. 29-133, 1984.

Armbruster T. Clinoptilolite-heulandite: applications and basic research. Studies in Surface Science and Catalysis 135, Zeolites and Mesoporous Materials at the Dawn of the 21st Century A. Galarnau, F. Di Renzo, F. Faujula and J. Vedrine (Editors), 2001.

Radosavljević-Mihajlović A. Karakterizacija i stabilnost dealuminisanih klinoptilolitskih tufova različitih ležišta, Magistarska teza, Fakultet fizičke hemije, Univerzitet u Beogradu, str. 30-41. 2004.

Radosavljević-Mihajlović A., Kašić V., Lemić J. Mineralogy and crystal chemistry of zeolitic tuffs from three deposits: Zlatokop, Beocin and Novakovici Buletin of Geoinstitute 2003, 38: 149-155.

Radosavljević-Mihajlović A., Stojanović J., Kašić V. Comparative mineralogical, crystallochemical and thermal features of Serbian zeolitic tuffs rich in HEU- type minrals, Buletin of Geoinstitute2005, 40: 191-200.

Barić Lj., Bull. Sci. Cons. Acad. Yougosl. 10/6, 177- 178, 1965.

Šoufek M., Tibljaš D., Zebec V., Slavković R. First Croatian Geological Congress, Book of Abstracts, Opatija Zagreb, 89, 1995.

Palinkaš L.A., Bermanec V., Borojević Šoštarić S., Kolar - Jurkovšek T., Strmić Palinkaš S., Molnar F., Kniewald G. Volcanic facies of a subaqucons basalt lava-flow complex at Hruskovec NW Croatia-Evidence of advanced rifting in the Tethyan domain, Journal of Volcanology and Geothremal Resarch2008, 178: 644-656.

Šćavničar B., Šćavničar S., Šušnjara A. Prirodoslovna istraživanja, 49, Acta Geol. 1984, 14(2): 35-82.

Braun K. Prirodoslovna istraživanja, 63, Acta Geol. 1991, 21(1): 1-34.

Slovenec D., Bermanec V. Sistematska mineralogija – mineralogija nesilikata, DENONA, Zagreb, 359, 2003.

Tibljaš D., Jelavić S. Zeolite deposits in Croatia, Proceedings of the 5th Serbian-Croatian-Slovenian Symposium on Zeolites, Zlatibor 2013.

Đorđević D., Stojanović D. Pojave zeolita u Bosni. Zemaljski muzej BIH, naučni skup. Sarajevo, 1988.

Groves A.W., Silicate analysis. A manual for geologists and chemists with chapters on check calculations and geochemical data. Second edition. With a foreword by Professor A. Holmes. George Allen & Unwin Ltd. London 1951.

Rodríguez-Carvajal J. Recent developments of the program FULLPROF.IUCr Commission on Powder Diffraction Newsletter, 26: 12–19. http://www.iucr.org/data/assets/pdf_file/0019/21628/cpd26.pdf 2001

Momma K., Izumi F. VESTA 3 for three-dimensional visualization of crystal, volometric and morphology data. J. Appl. Crystallogr.2011, 44: 1272-1276.

Protić Lj., Glamočanin D. Projekat detaljnih geoloških istraživanja ležišta tufa Novakovići kod Snjegotine, Rudarsko-Geološki Institut PrIjedor, 1998.

Kraus W., Nolze G. POWDER CELL - a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns. J. Appl. Cryst. 1996, 29: 301-303.

Allieti A., Brigatti M.F., Poppi L. Natural Ca-rich clinoptilolite (heulandites of groupe 3): new data and review, Neues Jahrb. Mineral. 1977, Monatsh., 493-501.

Rabdel Ruiz-Salvador A., Rodriguez-Fuentes G., Rubayo-Soneira J. Computer simulation of the local environment around aluminum atoms in clinoptilolite. A defect calculation approach. (1997) In Natural Zeolites 97, Program and Abstracts, 261-263. Ischia, Italy.

Koyama K., Takeuchi Y. Clinoptilolite: The distribution of potassium atoms and its role in thermal stability, Zeitschrift für Kristallographie 1977, 145: 216-239.

Alberti A. The crystal structures of two clinoptilolites. Tschermaks mineralogische und petrographische Mitteilungen 1975, 22: 25-37.

Smyth J.R., Spaid A.T., Bish D.L. Crystal structures of a natural and a Cs-exchanged clinoptilolite. Am. Mineral. 1990, 75: 522-528.

[30] Merkle A.B., Slaughter M. Determination and refinement of the structure of heulandite. Am. Mineral. 1968, 53: 1120-1138.

Baerlocher Ch., Meier W.M., Olson D.H. Atlas of zeolite farmework typs, Structure Commission of International Zeolite Association, Amsterdam, 2001.

Shannon R.D., Prewitt C.T. Effective ionic radii in oxides and fluorides. Acta Crystall. 1969, B25: 925-945.

Mumpton F.A. Clinoptilolite redefined, Am. Mineral. 1960, 45: 351-369.

Yang P., Armbruster T. X-ray single-crystal structure refinement of NH4-exchanged heulandite at 100 K, Eur. J. Mineral. 1998, 10: 461-471.

Bish D.L. Effects of exchangeable cation composition on the thermal expansion/contraction of clinoptilolite. Clay. Clay Miner. 1984, 32: 444-452.

Bish D.L. Long-term thermal stability of clinoptilolite: The development of a "B" phase. Eur. J. Mineral. 1990, 2: 771-777.

Bish D.L., Duffy C.J. Thermogravimetric analysis of Minerals. In CMS Workshop lectures, Vol. 3, Thermal Analysis in Clay Science (J. W. Stucki; D.L., Bish; F. A. Mumpton; editors). The Clay Minerals Society, 96-157. Boulder, Colorad, 1990.

Armbruster T. Dehydration mechanism of clinoptilolite and heulandite: Single-crystal X-ray study of Na-poor, Ca-, K-, Mg-rich clinoptilolite at 100 K. Am. Mineral. 1993, 78: 260-264.

Most read articles by the same author(s)

Similar Articles

You may also start an advanced similarity search for this article.