Uklanjanje toksične boje termički modifikovanim lignoceluloznim otpadom u trofaznom “air-lift” reaktoru: uvid u kinetiku procesa Naučni rad
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Ovaj rad istražuje uticaj protoka vazduha u trofaznom pneumatskom reaktoru sa recirkulacijom (air-lift) pri sorpciji toksične boje Brilliant Green, pomoću sorbenta na bazi bio čađ, i dobijenog od koštica višnje. U cilju karakterizacije sorbenta korišćene su sledeće metode: infracrvena spektroskopija sa Furijovom (Fourier) transformacijom i prigušenom totalnom refleksijom, pH vrednost suspenzije, tačka nultog naelektrisanja, skenirajuća elektronska mikroskopija sa energetski disperzivnom rendgenskom spektroskopijom i difrakcija rendgenskih zraka. Eksperimenti su izvedeni u air-lift reaktoru pri protoku vazduha od 2.50 i 5.55 dm3 h-1. Eksperimentalni podaci kinetike modelovani su nelinearnim oblicima pseudo-prvog i pseudo-drugog reda, kao i Weber-Morrisovim modelom, koji se zasniva na unutarčestičnoj difuziji. Pokazano je da je pri nižem protoku i intenzitetu mešanja, brzina sorpcije boje Brilliant Green ograničena brzinom prenosa mase ka sorbentu, dok je pri većem protoku rekacija kinetički kontrolisana u skadu sa pseudo-drugim kinetičkim modelom. Pored toga, pri nižem protoku, sorpcija je odložena usled otpora prenosa mase kroz granični sloj tečnosti oko čestica sorbenta. Prikazani rezultati jasno ukazuju da intenzitet protoka vazduha ima značajnu ulogu u ukupnoj kinetici sorpcije i podržavaju moguću primenu biočadji za efikasnu sorpciju boje Brilliant green.
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Ovaj rad je pod Creative Commons Aуторство-Nekomercijalno-Bez prerade 4.0 Internacionalna licenca.
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Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-47/2023-01/200023 -
Science Fund of the Republic of Serbia
Grant numbers 7439
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