Characterization of glycidyl methacrylate based magnetic nanocomposites

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Bojana M. Marković
Vojislav V. Spasojević
Aleksandra Dapčević
Zorica M. Vuković
Vladimir B. Pavlović
Danijela V. Randjelović
Aleksandra B. Nastasović


Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful amino-functionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.


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Marković, B. M., Spasojević, V. V., Dapčević, A., Vuković, Z. M., Pavlović, V. B., Randjelović, D. V., & Nastasović, A. B. (2019). Characterization of glycidyl methacrylate based magnetic nanocomposites. HEMIJSKA INDUSTRIJA (Chemical Industry), 73(1), 25–35.
Engineering of Materials - Polymers


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